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Original Articles

Calculation of absolute scattering phase shifts

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Pages 147-150 | Received 05 May 2005, Accepted 19 Jul 2005, Published online: 21 Feb 2007
 

Abstract

Use of a simple semiclassical estimate of Bessel function phase for arbitrary argument avoids the modulo π errors which the conventional approach tends to introduce into the calculation of absolute quantal phase shifts for high partial waves. This has significant implications for the direct quantum mechanical calculation of second virial coefficients at high temperatures.

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