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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 105, 2007 - Issue 5-7: A Special Issue In Honour of John M. Brown
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Original Articles

Diode laser absorption spectroscopy of the ν2 fundamental band of propadienone formed in a pyrolysis jet

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Pages 727-732 | Received 17 Nov 2006, Accepted 15 Jan 2007, Published online: 16 May 2007
 

Abstract

A rotationally resolved infrared spectrum of the transient molecule propadienone has been recorded in a low temperature jet using diode laser absorption spectroscopy. The molecule was generated by pyrolysis of acrylic anhydride. The spectrum arises from the intense C–O stretching mode of the molecule and several series of lines were identified using Loomis Wood plots. The most prominent series on the high frequency side of the band origin consists of both a- and b-type transitions.

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