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Spin Chemistry Meeting 2017

Same spectral signature in liquid-state and solid-state 1H photo-CIDNP NMR spectra of cyclohexanone

, , , & ORCID Icon
Pages 2756-2761 | Received 30 Apr 2018, Accepted 30 Jul 2018, Published online: 26 Aug 2018
 

ABSTRACT

For the first time, a 1H solid-state photo-CIDNP effect is reported. The effect is observed in frozen solution of cyclohexanone in 1,4-dioxane-d8 under magic-angle spinning and continuous irradiation by the full spectrum of a xenon arc lamp. The spectral features show close similarity with those observed by 1H liquid-state photo-CIDNP NMR.

GRAPHICAL ABSTRACT

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was supported by the Russian Science Foundation under grant 15-13-20035.

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