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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 117, 2019 - Issue 20: 10th Liblice Conference on the Statistical Mechanics of Liquids
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Liblice 2018 Special Issue

Anomalously high heat capacity of liquids: relation to structural properties

Pages 2786-2792 | Received 27 Sep 2018, Accepted 14 Nov 2018, Published online: 05 Dec 2018
 

ABSTRACT

Heat capacity of several liquids which demonstrate anomalous behaviour is studied. It is shown that isochoric heat capacity of these liquids shows anomalously high values which is related to smooth structural crossover in these liquids. This phenomenon can be used for qualitative explanation of high heat capacity of water and some other substances.

GRAPHICAL ABSTRACT

Acknowledgments

This work has been carried out using computing resources of the federal collective usage centre Complex for Simulation and Data Processing for Mega-science Facilities at NRC “Kurchatov Institute”, http://ckp.nrcki.ru/.

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

Part of the work was performed also at the cluster of Joint Supercomputing Center, Russian Academy of Science. This work was supported by the Russian Science Foundation [grant number 14-22-00093].

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