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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 16, 1969 - Issue 5
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Original Articles

The force and torque on nuclei of a molecule subjected to external fields

Pages 509-517 | Received 21 Jan 1969, Published online: 11 Aug 2006
 

Abstract

If a molecule is subjected to an external static electromagnetic field, the force and torque felt by the electrons are transmitted to the nuclei. An analogous result holds when the electromagnetic field is oscillatory. These results are applied to derive identities that may be used to test the quality of computations of static quadrupole and dynamic dipole polarizabilities.

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