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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 26, 1973 - Issue 3
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Original Articles

On the quantum corrections to the virial coefficients of the equation of state of a fluid

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Pages 539-547 | Received 11 Jan 1973, Published online: 23 Aug 2006
 

Abstract

The first quantum correction to the virial coefficients of the equation of state of a fluid is derived in the presence of a weak three-body potential ϕ(i, j, k). Results for the third and fourth virial coefficients are given. Representing the potential energy of interaction of a pair and a triplet, by the Lennard-Jones (12-6) model and the triple dipole dispersion potential model of Axilrod and Teller, the first quantum correction to the third virial coefficient is calculated for many values of T*. The theoretical result is compared with the experimental data of helium.

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