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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 34, 1977 - Issue 4
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Original Articles

Nuclear relaxation, molecular motions and interactions

Part 1. 14N nuclear quadrupole relaxation from the 1H line-shape analysis of pyrrole and its several non-aqueous solutions

Halina M. Ratajczak Department of Chemistry and Applied Chemistry, University of Salford, Salford, M5 4WT, United KingdomView further author information
,
John A. Ladd Department of Chemistry and Applied Chemistry, University of Salford, Salford, M5 4WT, United Kingdom
,
W.J. Orville-Thomas Department of Chemistry and Applied Chemistry, University of Salford, Salford, M5 4WT, United Kingdom
&
Henryk Ratajczak Institute of Chemistry, University of Wroclaw, 50-383, Wroclaw, Poland
Pages 1019-1025 | Received 09 May 1977, Published online: 22 Aug 2006
 
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Abstract

The 14N quadrupolar relaxation time for pyrrole as the pure liquid and in solution in 1,4-dioxan, pyridine, 3,5-lutidine and 2-fluoropyridine has been determined from the line-shape analysis of the imido proton magnetic resonance signal. The dependence of the line shape on solute concentration and temperature was studied and the activation parameters for molecular reorientation determined.

Additional information

Notes on contributors

Halina M. Ratajczak

On leave from the Institute of Chemistry, University of Wroclaw, Poland.

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