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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 34, 1977 - Issue 6
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Original Articles

Saturation spectroscopy in I2 with spatially separate beams

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Pages 1523-1529 | Received 06 Dec 1976, Published online: 22 Aug 2006
 

Abstract

A new technique for measuring the dynamic friction coefficient η in a gas sample at low pressure is described. By varying the distance between two spatially separate antiparallel laser beams in a saturable absorber, we are able to follow the dynamics of the Bennett hole and resonant spike, caused by non-linear absorption, in the molecular velocity distribution. Iodine in the presence of 1 torr of argon buffer gas is studied using an Ar+ laser, and η is found to be approximately 2000 s-1, corresponding to a 10-3 fractional change in velocity in one collision. The technique is capable in principle of measuring diffusion coefficients and fluorescence lifetimes, and it involves information on both the ground and excited states.

Supported by the National Science Foundation.

Supported by the National Science Foundation.

Notes

Supported by the National Science Foundation.

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