Publication Cover
Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 33, 1977 - Issue 1
6
Views
7
CrossRef citations to date
0
Altmetric
Original Articles

Incoherent scattering law for dynamically independent molecular and intramolecular reorientations in (CH3)3NHCl

Pages 125-131 | Received 13 Apr 1976, Published online: 22 Aug 2006
 

Abstract

A jump model is developed which describes simultaneous, dynamically uncorrelated reorientational motions of a proton about two different threefold axes. For the spectrum of quasielastic neutron scattering a superposition of three lorentzians with linewidths of 1/τ1, 1/τ2, and 1/τ*=1/τ1 + 1/τ2 is obtained as quasielastic broadening. The model is applied to describe the reorientations of the cation (CH3)3NH+ and of the CH3 groups in (CH3)3NH+Cl-.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.