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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 36, 1978 - Issue 4
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Original Articles

Quasiclassical dynamics of Jahn-Teller molecules

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Pages 1069-1084 | Received 19 Dec 1977, Published online: 23 Aug 2006
 

Abstract

A two-dimensional model of a Jahn-Teller system with strong first and weak second-order vibronic coupling is analysed. Separation of the variables r and φ is achieved in the adiabatic approximation for the angular motion.

The positions of deep quasi-classical levels and their splittings, due to tunnelling and over-barrier reflection of the orbital motion in the periodic potential are found.

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