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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 37, 1979 - Issue 2
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Original Articles

Non-additive interactions in liquid helium solvent effects

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Pages 599-606 | Received 13 Feb 1978, Published online: 23 Aug 2006
 

Abstract

The Sinanoğlu solvent effect method is here modified to include the exchange-overlap three-body SCF term in addition to the usual triple-dipole term. This is accomplished using an analytical fit which gives a better picture of short range non-additive interactions. The application of this modified model to the dimers (4He)2, (3He)2 and 3He-4He in a liquid 4He environment leads to the lowering of the effective-pair potential energy curve. As a consequence the new terms play a significant role, within the limitations of the method, in the calculation of a bound state of helium dimers immersed in a liquid helium medium.

Additional information

Notes on contributors

O. Novaro

Consultant of Instituto Mexicano del Petróleo.

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