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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 37, 1979 - Issue 5
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Original Articles

Calculation of effective hamiltonians using quasi-degenerate Rayleigh-Schrödinger perturbation theory (QD-RSPT)

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Pages 1455-1468 | Received 07 Jul 1978, Published online: 23 Aug 2006
 

Abstract

The quasi-degenerate Rayleigh-Schrödinger perturbation theory (QD-RSPT) proposed by Brandow [3] is rederived in matrix form. An approximate computational method is proposed which includes the diagonal energy renormalizations (the diagonal folded diagrams) to infinite order. Several numerical examples are presented which illustrate the numerical stability of the method.

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