Advanced search
Publication Cover
Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 41, 1980 - Issue 1
Submit an article Journal homepage
650
Views
1,276
CrossRef citations to date
0
Altmetric
Original Articles

Elucidation of cross relaxation in liquids by two-dimensional N.M.R. spectroscopy

S. Macura Laboratorium für Physikalische Chemie, Eidgenössische Technische Hochschule, 8092, Zürich, Switzerland; Institute of Physical Chemistry, Faculty of Sciences, 11000, Beograd, YugoslaviaView further author information
&
R.R. Ernst Laboratorium für Physikalische Chemie, Eidgenössische Technische Hochschule, 8092, Zürich, Switzerland
Pages 95-117 | Received 19 Mar 1980, Published online: 18 Sep 2006
 
Sample our Mathematics & Statistics journals, sign in here to start your FREE access for 14 days

Abstract

Two-dimensional N.M.R. spectroscopy is applied to the elucidation of cross relaxation pathways in liquids. The theory underlying two dimensional studies of cross relaxation and of transient nuclear Overhauser effects is developed. The influence of the correlation time of the molecular random process is investigated. It is found that in the limit of short correlation times (extreme narrowing limit) weak negative cross-peaks are observed. However, for long correlation times (spin diffusion limit) strong positive cross-peaks can be obtained. The technique appears particularly promising for the study of cross relaxation in macromolecules. Examples of intra- and intermolecular cross relaxation in the extreme narrowing limit are presented.

Additional information

Notes on contributors

S. Macura

Academic Guest 1979–1980

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Molecular photochromic systems: a theoretical and experimental investigation on zinc(II) dithizonate
Source: Wiley
Delineation of conformational preferences in human salivary statherin by 1H, 31P NMR and CD studies: sequential assignment and structure-function correlations.
Source: Informa UK Limited
Synthesis, Interionic Structure, and Reactivity toward CO and p-Methylstyrene of Palladacyclic Compounds Bearing α-Diimine Ligands
Source: Wiley
Interaction between cellohexaose and cellulose binding domains from Trichoderma reesei cellulases.
Source: Federation of European Biochemical Societies. Published by Elsevier B.V.
Imino-proton resonances of yeast tRNAPhe studied by two-dimensional nuclear Overhauser enhancement spectroscopy.
Source: Wiley
The N Terminus of Connexin37 Contains an α-Helix That Is Required for Channel Function
Source: American Society for Biochemistry & Molecular Biology (ASBMB)
Covariance NMR in higher dimensions: application to 4D NOESY spectroscopy of proteins.
Source: Springer Science and Business Media LLC
NMR studies of backbone-alkylated DNA: duplex stability, absolute stereochemistry, and chemical shift anomalies of prototypal isopropyl phosphotriester modified octanucleotides, (Rp,Rp)- and (Sp,Sp)-(d-[GGA(iPr)ATTCC])2 and -(d-[GGAA(iPr)TTCC])2.
Source: Informa UK Limited
Lipid-induced conformation of substance P.
Source: Informa UK Limited
Structure and conformation of the duplex consensus acceptor exon:intron junction d[(CpTpApCpApGpGpT). (ApCpCpTpGpTpApG)] deduced from high-field 1H-NMR of non-exchangeable and imino protons.
Source: Informa UK Limited
Synthesis and biological activity of an Anderson polyoxometalate bis‐functionalized with a Bombesin‐analog peptide
Source: Wiley
Sequence specific molecular recognition and binding by a GC recognizing Hoechst 33258 analogue to the decadeoxyribonucleotide d-[CATGGCCATG]2: structural and dynamic aspects deduced from high field 1H-NMR studies.
Source: Informa UK Limited
Accounting for the temperature dependence of 13C spin–lattice relaxation of methyl groups in the glycyl–alanyl-leucine model system under MAS with spin diffusion
Source: Springer Science and Business Media LLC
Structure elucidation and 3D solution conformation of the antibiotic enduracidin determined by NMR spectroscopy and molecular dynamics.
Source: Wiley
The cavity in the hydrophobic core of Myb DNA-binding domain is reserved for DNA recognition and trans-activation.
Source: Springer Science and Business Media LLC
Linear-scaling ab initio simulations of spin diffusion in rotating solids.
Source: AIP Publishing
Use of carbon–carbon nuclear spin diffusion for the study of the miscibility of polymer blends
Source: AIP Publishing
Improved two-dimensional J-resolved spectroscopy.
Source: Wiley
The solution structure of yeast tRNAPhe as studied by nuclear Overhauser effects in NMR.
Source: Informa UK Limited
Liquid Metastable Precursors of Ibuprofen as Aqueous Nucleation Intermediates.
Source: Weinheim : Wiley-VCH Verlag
Conformation and Biological Activity of Cyclic Peptides
Source: Wiley
INFLUENCE OF LITHIUM CATIONS
Source: Wiley
Structure of a tumor associated antigen containing a tandemly repeated immunodominant epitope.
Source: Informa UK Limited
Structure and conformation of the branch core triribonucleotide containing 2'-5' and 3'-5' phosphodiester linkages (A 2'p5'G 3'p5'C) i solution, essential for yeast mRNA splicing, deduced from 1H-NMR.
Source: Informa UK Limited
[Ala4]surfactin, a novel isoform from Bacillus subtilis studied by mass and NMR spectroscopies.
Source: HAL CCSD
Coherent two-dimensional terahertz-terahertz-Raman spectroscopy
Source: Proceedings of the National Academy of Sciences
Warum pentose-und nicht hexose-nucleinsäuren? Teil III. Oligo(2′,3′-dideoxy-β-D-glucopyranosyl) nucleotide (‘homo-DNS’): Paarungesigenschaften†‡
Source: Wiley
Isolation and characterization of a new variant of surfactin, the [Val7]surfactin.
Source: HAL CCSD
Conformational and model-building studies of the hairpin form of the mismatched DNA octamer d(m5C-G-m5C-G-T-G-m5C-G).
Source: Informa UK Limited
Theory of covariance nuclear magnetic resonance spectroscopy.
Source: AIP Publishing
Pre-organization of the Core Structure of E-Selectin Antagonists
Source: Wiley
Sequence dependent conformation and local geometry of the conserved branch site sequence element d(TpApCpTpApApC), essential for yeast mRNA splicing, deduced from high resolution 1H-NMR.
Source: Informa UK Limited
Flüssige metastabile Vorstufen von Ibuprofen als Zwischenprodukt der Nukleation in wässriger Lösung
Source: Wiley
An acidity scale of phosphonium tetraphenylborate salts and ruthenium dihydrogen complexes in dichloromethane
Source: Canadian Science Publishing
Automated Structure Determination from NMR Spectra
Source: Springer Science and Business Media LLC
NMR Study of Spatial Structure and Internal Dynamic of Adducts of Ninhydrin-Derived Azomethine Ylide with Cyclopropenes
Source: Springer Science and Business Media LLC
Synthesis, aggregation and adsorption behaviour of a thermoresponsive pentablock copolymer
Source: Wiley
Sequence specific molecular recognition and binding of a monocationic bis-imidazole lexitropsin to the decadeoxyribonucleotide d-[(GATCCGTATG).(CATACGGATC)]: structural and dynamic aspects of intermolecular exchange studied by 1H-NMR.
Source: Informa UK Limited
Structure and conformation of the duplex consensus 5'-splice site d[(CpApGpGpTpApApGpT).(ApCpTpTpApCpCpTpG)] deduced from high field 1H-NMR of the non-exchangeable and imino protons.
Source: Informa UK Limited
The minimal tRNA: unique structure of Ascaris suum mitochondrial tRNASerUCU having a short T arm and lacking the entire D arm
Source: Federation of European Biochemical Societies. Published by Elsevier B.V.
Aggregation tendency and reactivity toward AgX of cationic half-sandwich ruthenium(II) complexes bearing neutral N,O-ligands.
Source: Royal Society of Chemistry (RSC)
A heteronuclear correlation experiment for simultaneous determination of 15N longitudinal decay and chemical exchange rates of systems in slow equilibrium.
Source: Springer Science and Business Media LLC
Structure of bacillomycin F, a new peptidolipid antibiotic of the iturin group
Source: Wiley
Conclusive evidence that the major T-cell antigens of the Mycobacterium tuberculosis complex ESAT-6 and CFP-10 form a tight, 1:1 complex and characterization of the structural properties of ESAT-6, CFP-10, and the ESAT-6*CFP-10 complex. Implications for pathogenesis and virulence.
Source: American Society for Biochemistry & Molecular Biology (ASBMB)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.