Molecular motions in liquid NOF₃

P. Nectoux Département de Physico-Chimie, Centre d'Etudes Nucléaires de Saclay, 91190, Gif/Yvette, France

M. Gilbert Département de Physico-Chimie, Centre d'Etudes Nucléaires de Saclay, 91190, Gif/Yvette, France

M. Drifford Département de Physico-Chimie, Centre d'Etudes Nucléaires de Saclay, 91190, Gif/Yvette, France

Abstract

The rotational behaviour of NOF₃ is derived from the band contour analysis of the Raman spectra recorded over the liquid phase. The angular momentum correlation times derived from the J diffusion model show us that this C _3v molecule rotates almost isotropically. The band profiles are interpreted in terms of the rough hard sphere model.

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Molecular motions in liquid NOF₃

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Molecular motions in liquid NOF3

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Molecular motions in liquid NOF₃