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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 42, 1981 - Issue 4
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Original Articles

A remark on the Percus-Yevick approximation in higher dimensions

Hard core systems

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Pages 927-936 | Received 17 Sep 1980, Accepted 03 Nov 1980, Published online: 23 Aug 2006
 

Abstract

The five dimensional Ornstein-Zernike equation is Wiener-Hopf factorized following Baxter [1]. This formalism is then applied to five dimensional hard hyperspheres to yield an analytic result in the Percus-Yevick (PY) closure approximation. In addition, the scaled particle result for that system is also derived. The first few virial coefficients are also calculated. Apparently, the PY virial and compressibility pressures bracket the true result. Perturbative treatments for potentials with attractive tails are briefly discussed.

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