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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 42, 1981 - Issue 6
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Original Articles

Non-equilibrium molecular dynamics study of the rheological properties of diatomic liquids

Denis J. Evans Research School of Physical Sciences, Australian National University, P.O. Box 4, Canberra, A.C.T., 2600, Australia; Thermophysical Properties Division, National Bureau of Standards, Boulder, Colorado, 80309, U.S.A.
Pages 1355-1365 | Received 23 Sep 1980, Accepted 29 Dec 1980, Published online: 23 Aug 2006
 
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Abstract

We use non-equilibrium molecular dynamics to calculate the shear and vortex viscosity coefficients and the shear induced birefringence coefficient of a model diatomic liquid, liquid chlorine. We also calculate the complex frequency dependent vortex viscosity. Phenomenological equations are presented which describe the linear, zero frequency hydrodynamics of such fluids.

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