Effect of solvents on carbon-13 spin-lattice relaxation in 1-phenyladamantane

Robin K. Harris School of Chemical Sciences, University of East Anglia, Norwich, NR4 7TJ, England

Roger H. Newman School of Chemical Sciences, University of East Anglia, Norwich, NR4 7TJ, England; Chemistry Division, DSIR, Private Bag, Petone, New Zealand

Abstract

Rotational diffusion of 1-phenyladamantane was studied by means of carbon-13 spin-lattice relaxation. Seven different solvents were used. Rotational correlation times showed a linear dependence on solvent viscosity, except for chloroform and 1,1,2,2-tetrachloroethane which retarded motion of the phenyl moiety through specific interactions.

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Effect of solvents on carbon-13 spin-lattice relaxation in 1-phenyladamantane

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Effect of solvents on carbon-13 spin-lattice relaxation in 1-phenyladamantane

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