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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 47, 1982 - Issue 4
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Original Articles

Second virial coefficients for a fluid of dipolar hard ellipsoids

Pages 771-783 | Received 19 Apr 1982, Accepted 26 May 1982, Published online: 11 Aug 2006
 

Abstract

We calculate the two body contributions to the pressure, dielectric constant, depolarized light scattering intensity, electro-optical birefringence (Kerr effect), and other properties, of a fluid whose molecules are hard ellipsoids with embedded central point dipoles. The results are presented for various molecular anisotropies and dipole strengths. The second dielectric and Kerr virial coefficients are found to be particularly sensitive to molecular shape.

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