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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 49, 1983 - Issue 1
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Original Articles

The extension of pure fluid thermodynamic properties to supercritical mixtures

A comparison of current theories with computer data over a large region of states

, &
Pages 159-170 | Received 14 Oct 1982, Accepted 13 Dec 1982, Published online: 23 Aug 2006
 

Abstract

Current theories to extend pure fluid thermodynamic properties to supercritical mixtures have been examined by comparison with computer data. Emphasis is placed on a large variation of potential parameter ratios and density. It is found that, while the VDW1 approximation is generally the best, its predictions are considerably poorer at supercritical conditions than in the normal liquid range.

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