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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 52, 1984 - Issue 5
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Original Articles

Ornstein-Zernike equation for a two-Yukawa c(r) with core condition

III. A self-consistent approximation for a pair potential with hard core and Yukawa tail

&
Pages 1071-1079 | Received 23 Dec 1983, Accepted 10 Feb 1984, Published online: 22 Aug 2006
 

Abstract

We use the results of previous papers in this series to formulate a new self-consistent Ornstein-Zernike approximation for the radial distribution function of a system of particles interacting via a pair potential with a hard core and tail of Yukawa form. The approximation scheme is entirely self-contained, requiring no thermodynamic or other supplementary input. Preliminary results for a simplified version of the scheme that is applicable to a lattice gas yield critical-region thermodynamics in strikingly good agreement with the best current estimates of three dimensional lattice-gas critical behaviour.

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