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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 54, 1985 - Issue 1
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Original Articles

Multipole polarizabilities and hyperpolarizabilities of the charged harmonic oscillator

Pages 129-139 | Received 30 Jul 1984, Accepted 14 Sep 1984, Published online: 23 Aug 2006
 

Abstract

The polarizabilities describing the response of the multipole moments of a charged harmonic oscillator to a field and field gradient are calculated exactly, without recourse to perturbation theory. Generalizations of the Kirkwood and Unsöld treatments for multipole polarizabilities are given, and found to be exact for the harmonic oscillator. Changes in the multipole polarizabilities on confinement of the oscillator to a spherical box are also calculated.

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