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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 54, 1985 - Issue 3
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Original Articles

Anomalous 14N quadrupole coupling constant of methyl isocyanide in liquid crystals

Thomas M. Barbara Department of Chemistry, University of California, San Diego, La Jolla, California, 92093, U.S.A.; School of Chemical Sciences, University of Illinois, 19-5 Roger Adams Lab., 1209 W. California, Urbana, Illinois, 61801, U.S.A.
Pages 651-656 | Received 21 Sep 1984, Accepted 26 Oct 1984, Published online: 23 Aug 2006
 
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Abstract

The 14N quadrupole coupling constant (QCC) for methyl isocyanide obtained from 1H and 14N N.M.R. measurements in liquid crystal solutions is reported as a function of temperature for two liquid crystal solvents. A marked linear temperature dependence is observed in both solvents. The measured QCC varies by 20 per cent over a 50°C range.

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