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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 54, 1985 - Issue 5
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Original Articles

Renormalized perturbation theory for dipolar and quadrupolar polarizable liquids

, &
Pages 1117-1128 | Received 03 Sep 1984, Accepted 27 Sep 1984, Published online: 23 Aug 2006
 

Abstract

We derive the equations which determine the free energy, and other thermodynamic and structural properties, including the high-frequency dielectric constant, of a dipolar-quadrupolar polarizable liquid at the second level of renormalized perturbation theory (2-RPT). Our treatment is non-graphical and is based on simple arguments from electrostatics. The significance of the various parameters which enter the renormalized theory is discussed. Our results provide the starting point for calculations of the effects of many-body induction forces in molecular liquids.

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