Abstract
High resolution FTIR spectra of 2-fluoro, 2-methylpropane have been measured and analysed in the region of the CF-chromophore absorption (800 cm-1 to 1300 cm-1). Spectra with a resolution of 0·02 cm-1 have been obtained at room temperature and reduced temperatures near 213 K. Rotational and vibrational assignments have been obtained for the three strong fundamentals and two hot bands in this region (the spectroscopic parameters are summarized in table 4). The results are discussed in terms of the group additivity rule for the integrated band strength of the CF-chromophore and in relation to subpicosecond vibrational redistribution after local vibrational excitation.
Presented at the 8th International Conference on High Resolution Infrared Spectroscopy, Prague, September 1984.
Presented at the 8th International Conference on High Resolution Infrared Spectroscopy, Prague, September 1984.
Notes
Presented at the 8th International Conference on High Resolution Infrared Spectroscopy, Prague, September 1984.