Publication Cover
Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 56, 1985 - Issue 2
23
Views
3
CrossRef citations to date
0
Altmetric
Original Articles

High resolution FTIR spectra and assignment of the vibrational structure in the CF-chromophore region in (CH3)3CF

, &
Pages 463-477 | Received 08 May 1985, Accepted 08 Jun 1985, Published online: 23 Aug 2006
 

Abstract

High resolution FTIR spectra of 2-fluoro, 2-methylpropane have been measured and analysed in the region of the CF-chromophore absorption (800 cm-1 to 1300 cm-1). Spectra with a resolution of 0·02 cm-1 have been obtained at room temperature and reduced temperatures near 213 K. Rotational and vibrational assignments have been obtained for the three strong fundamentals and two hot bands in this region (the spectroscopic parameters are summarized in table 4). The results are discussed in terms of the group additivity rule for the integrated band strength of the CF-chromophore and in relation to subpicosecond vibrational redistribution after local vibrational excitation.

Presented at the 8th International Conference on High Resolution Infrared Spectroscopy, Prague, September 1984.

Presented at the 8th International Conference on High Resolution Infrared Spectroscopy, Prague, September 1984.

Notes

Presented at the 8th International Conference on High Resolution Infrared Spectroscopy, Prague, September 1984.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.