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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 56, 1985 - Issue 4
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Original Articles

Ã2Σ+[Xtilde]2Πi emission spectra of the thioborine cations HBS+ and DBS+

, , , &
Pages 871-885 | Received 05 Jul 1985, Accepted 31 Jul 1985, Published online: 26 Oct 2007
 

Abstract

The emission spectra of the à 2Σ+[Xtilde] 2Π i transitions of HBS+ and DBS+ have been obtained by electron impact excitation. A vibronic analysis of the band systems has been made and the vibrational frequencies of the three modes in the [Xtilde] 2Π i state, and two in the à 2Σ+ state have been obtained for various isotopic derivatives. Renner and Fermi resonance effects of the bands involving the excitation of the ν2/″ mode have been considered and the parameters characterizing these interactions evaluated.

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