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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 58, 1986 - Issue 5
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Original Articles

N.M.R. study of the 125Te shielding anisotropy of tellurophene dissolved in various nematic liquid crystals

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Pages 959-964 | Received 19 Feb 1986, Accepted 25 Feb 1986, Published online: 22 Aug 2006
 

Abstract

The 125Te N.M.R. spectrum of tellurophene in three liquid crystals was recorded and analysed. The different orientational behaviour of tellurophene in the liquid crystals enabled the anisotropy of the tellurium-125 shielding tensor, σ zz - 1/2(σ xx + σ yy ), and the difference σ xx - σ yy of the tensor elements to be determined. The resulting values are -1569 ± 21 ppm and 307 ± 26 ppm, respectively. The analysis of the 125Te N.M.R. spectra is also discussed.

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