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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 59, 1986 - Issue 4
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Original Articles

High frequency elastic moduli of colloidal dispersions

Pages 737-751 | Received 09 Jun 1986, Accepted 03 Jul 1986, Published online: 22 Aug 2006
 

Abstract

A perturbation theory for the high frequency elastic moduli of colloidal dispersions is developed using an inverse power potential reference fluid. When supplemented by a random phase approximation for the perturbation potential, the theory can be used to determine rheological properties of disordered colloidal dispersions from observed structure factors. The theory is applied to measurements of the structure factor for an aqueous dispersion of polystyrene latex spheres at the order-disorder transition. The calculated properties are found to be in good agreement with independent experimental measurements.

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