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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 62, 1987 - Issue 4
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Original Articles

Hard sphere fluids near a hard wall and a hard cylinder

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Pages 861-874 | Received 13 May 1987, Accepted 14 Jul 1987, Published online: 23 Aug 2006
 

Abstract

The local structure of a hard sphere fluid near a hard wall and near a hard cylinder is investigated using the Monte Carlo method. Near the wall we find a reduction in the average fluid density, and in the normal diffusivity. The simulation results are compared with the predictions of a density functional model. In this model the local density profile of a hard sphere fluid can be calculated in d-dimensional symmetry for any real symmetry dimension.

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