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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 62, 1987 - Issue 6
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Original Articles

Spin 1 and 3/2 systems in quadrupole fields

Pages 1409-1418 | Received 22 Oct 1986, Accepted 17 Jul 1987, Published online: 23 Aug 2006
 

Abstract

We study the Unitary evolution of spin 1 and 3/2 systems in an arbitrary external quadrupole field. Explicit solutions in closed form are obtained. These are employed to examine the notion of ‘ precession ’ of the vector polarization P = ⟨J⟩ in the field. Finally, in view of the large number of invariants that we find, we develop a method based on the lagrangian formulation using which, and without having to solve the equations of motion, the invariants can be discovered when a (quantum) statistical assembly evolves in an external field.

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