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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 63, 1988 - Issue 4
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Original Articles

Application of the rotational isomeric model to the calculation of binary interactions between flexible chains

II. Collision integrals and viscosity coefficients of n-alkanes

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Pages 601-609 | Received 14 Oct 1987, Accepted 11 Nov 1987, Published online: 26 Oct 2007
 

Abstract

The collision integrals and low density viscosity coefficients of n-alkane chains in the range n = 4–9 at several different temperatures have been calculated within the frame of the Mason and Monchick approximation. These computations are based on numerical intermolecular potentials obtained for Monte Carlo samples of pairs of conformations with randomly chosen relative orientations. The conformations are built according to the rotational isomeric model and the interactions are computed assuming a site-site LJ potential, as specified in the preceding paper. The averaged viscosity values are compared with experimental data. From this comparison the consistency of the model and the validity of the method are discussed.

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