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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 63, 1988 - Issue 4
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Original Articles

Local-mode to normal-mode hamiltonian transformation for X-H stretchings

Pages 611-621 | Received 12 Oct 1987, Accepted 14 Nov 1987, Published online: 26 Oct 2007
 

Abstract

The relationship between the local-mode and the normal-mode treatments of X-H stretchings is analysed by expressing the hamiltonian in terms of boson operators and transforming the operators rather than the basis functions. The transformation is exact, non-perturbative, and solves in a general form the open problem of the mathematical link between the two theories.

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