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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 63, 1988 - Issue 4
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Original Articles

Structure, thermodynamics, and orientational correlations of the nematogenic hard ellipse fluid from the Percus-Yevick equation

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Pages 623-638 | Received 18 Jun 1987, Accepted 13 Nov 1987, Published online: 26 Oct 2007
 

Abstract

The Percus-Yevick equation is solved for a fluid of hard ellipses in two dimensions. The correlation functions, including the orientation correlation function, are expanded in a set of orthogonal functions and the expansion coefficients are obtained by an iterative algorithm. Pressure and compressibility values are also determined. Orientational ordering is observed, but the isotropic-nematic phase transition observed by Vieillard-Baron (1972, J. chem. Phys., 56, 4729) is not.

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