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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 63, 1988 - Issue 4
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Original Articles

Equation of state of planar hard dumbells

Pages 685-690 | Received 28 Jul 1987, Accepted 22 Oct 1987, Published online: 26 Oct 2007
 

Abstract

An extension of the hard disc equation of state to planar hard dumbells is proposed and the determination of the characteristic geometric measures of dumbells with the reduced length L* ⩽ ⅈ2 is discussed. The second and third virial coefficients following from the proposed equation of state are evaluated and compared with the exact Monte Carlo data. Compressibility factors for four different elongations are calculated and compared with pseudoexperimental data and with results of other methods.

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