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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 66, 1989 - Issue 1
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Original Articles

Reduced density matrices and reduced local operators for a rotating-vibrating molecule

Pages 113-127 | Received 12 May 1988, Accepted 01 Sep 1988, Published online: 26 Oct 2007
 

Abstract

New concepts useful in studying the dynamics of a rotating-vibrating molecule are proposed. The rotational and vibrational reduced density matrices and reduced local operators which are introduced give clear and significant information about the rovibrational states of a molecule. A rotation-vibration correlation in some rovibrational states is revealed.

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