Study of angular correlation by N.M.R. of magnetically aligned molecules

E.W. Bastiaan Department of Physical Chemistry, Vrije Universiteit, De Boelelaan 1083, 1081 HV, Amsterdam, The Netherlands

L. Huis Department of Physical Chemistry, Vrije Universiteit, De Boelelaan 1083, 1081 HV, Amsterdam, The Netherlands

C. MacLean Department of Physical Chemistry, Vrije Universiteit, De Boelelaan 1083, 1081 HV, Amsterdam, The Netherlands

Abstract

A theoretical description of angular correlation in N.M.R. of diamagnetically aligned molecules is presented. High field deuterium N.M.R. is employed to study solutions of benzene, naphthalene and anthracene in binary mixtures of cyclohexane and hexafluorobenzene. Strong orientational cross correlation between the aromatic hydrocarbons and hexafluorobenzene is detected.

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Study of angular correlation by N.M.R. of magnetically aligned molecules

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Study of angular correlation by N.M.R. of magnetically aligned molecules

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