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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 68, 1989 - Issue 6
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Original Articles

A theoretical study of coherence transfer by isotropic mixing

Calculation of pulse sequence performance for systems of biological interest

, &
Pages 1191-1218 | Received 05 Jun 1989, Accepted 11 Aug 1989, Published online: 23 Aug 2006
 

Abstract

Computer simulations of coherence transfer functions under the isotropic mixing hamiltonian are presented for amino acids and the deoxyribose moiety in DNA. They allow the determination of the optimum mixing time in a two-dimensional TOCSY experiment. The effects of experimental parameters and pulse imperfections are discussed for practical pulse sequences.

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