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Molecular Physics

An International Journal at the Interface Between Chemistry and Physics

Volume 70, 1990 - Issue 3

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Original Articles

Spontaneous strain energies associated with orientational order-disorder phase transitions

Martin T. Dove Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge, CB2 3EQ, U.K.

Pages 425-431 | Received 28 Nov 1989, Accepted 08 Mar 1990, Published online: 22 Aug 2006

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https://doi.org/10.1080/00268979000101091

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Abstract

The contributions to the excess free energies of the orientational order-disorder phase transitions from the associated lattice distortions (spontaneous strains) in SF₆ and calcite have been calculated. These contributions are about one-third of the total excess free energies in both cases.

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