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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 86, 1995 - Issue 4
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Original Articles

Development of periodic order in disordered surfactant-solution phases

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Pages 675-684 | Received 14 Mar 1995, Accepted 14 Apr 1995, Published online: 23 Aug 2006
 

Abstract

The scattering peak in an isotropic surfactant solution evolves into a Bragg diffraction peak as the isotropic solution undergoes a transition to a neighbouring lamellar liquid crystalline phase. The scattering peak in the isotropic phase may thus be viewed as premonitory: the dominant fluctuations of structure and composition in the isotropic phase anticipate the transition to the lamellar phase. The phenomenon is illustrated here in a lattice model of surfactant solutions that had been proposed earlier.

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