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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 87, 1996 - Issue 2
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Original Articles

Stiffness matrix formalism for wetting transitions

I. Short-range forces

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Pages 501-515 | Received 24 Aug 1995, Accepted 27 Sep 1995, Published online: 23 Aug 2006
 

Abstract

Recent studies of complete wetting by a simple fluid at a planar substrate (wall) have emphasized the rôle of coupling between order parameter fluctuations near the wall and the depinning interface. These are modelled by a two-field effective Hamiltonian H 2[l 1, l 2] characterized by a stiffness matrix Σ(l 1, l 2). The deep relationship between such model Hamiltonians and mean-field order-parameter correlations is reformulated in a simple matrix language and used to study details of correlation function structure related to the coupling of fluctuations. We uncover some new features of correlation function behaviour near the complete wetting transition, making connection with long-standing results and conjectures, and point out the significance of pairs of poles and zeros of the corresponding structure factor.

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