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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 94, 1998 - Issue 1
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Original Articles

Electron correlation and quantum electrodynamics

Pages 19-28 | Published online: 06 Dec 2010
 

Abstract

A review is given of the coupled-cluster approach for a multi-reference model space. Various schemes of normalization are discussed, particularly the hermitian formulation. Relativistic many-body schemes are analysed, starting from the no-virtual-pair approximation (NVPA). Effects beyond NVPA are discussed in the framework of QED, and in particular the QED effects on the electron correlation for He-like ions are analysed.

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