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Original Articles

Supersaturation, the Spinodal, and Their Prediction Using Equations of State

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Pages 643-661 | Received 18 Aug 1999, Published online: 24 Sep 2006
 

Abstract

The equations of state of Redlich-Kwong, Soave, BWR, Schmidt-Wenzel, and Harmens-Knapp have been tested and compared in their ability to predict the spinodal and the experimental limits of superheat of pure liquids. The results indicate that only the Peng-Robinson, Soave and BWR equations are capable of predicting reduced kinetic limits of supersaturation above the experimental ones.

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