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Original Articles

Studies on the catalysis by lithium perchlorate and lithium trifluoromethanesulfonate of the photo-oxidation of phenols and α-phellandrene in different solvents

, &
Pages 663-673 | Received 03 Mar 2007, Accepted 04 May 2007, Published online: 05 Oct 2007
 

Abstract

The catalytic effect of aqueous solutions of lithium perchlorate and lithium trifluoromethanesulfonate on the photochemical oxidation of various phenols has been studied. Additionally, the increase of the yield of studied reactions has been observed in weakly alkaline aqueous solutions in comparison to the neutral ones. The analogous catalytic effect of 4 M or 2 M solutions in Et2O and CH2Cl2 of lithium perchlorate and lithium trifluoromethanesulfonate on the reaction of α-phellandrene with singlet oxygen has been also observed.

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