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Original Articles

Osmotic Pressure Related to Concentration Fluctuations, With Application to Liquid Metal Alloys

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Pages 155-168 | Received 02 Jul 1985, Published online: 19 Dec 2006
 

Abstract

An integral equation is first set up which allows the osmotic pressure to be calculated from knowledge of (a) the concentration fluctuations and (b) the equations of state of the two pure liquids 1 and 2 which are constituents of the binary 1-2 mixture. The method is illustrated by approximate numerical calculations on a variety of liquid binary mixtures, including Na-Ga and Na-Cd under pressure.

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