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Physics and Chemistry of Liquids
An International Journal
Volume 26, 1993 - Issue 3
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Articles

Effective Atomic Diameter Changes on Mixing Liquid Metals

B. Karaoglu Department of Physics, College of Science, Sultan Qaboos University, P O Box 32486 Al-Khod, Muscat, Sultanate of Oman
Pages 179-184 | Received 09 Mar 1993, Published online: 24 Sep 2006
 
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Abstract

A simple model based on the variational Gibbs-Bogotiubov method is used to investigate the manner in which the effective hard sphere diameters change on mixing liquid metals. It implies that in general the diameter of the ions with lower pure liquid valence electron density contracts while the other expands, provided the bare pseudopotentials are unaffected by alloying.

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