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Polymer News
The Polymer Science Monthly
Volume 29, 2004 - Issue 7
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Original Articles

Short Communication: The "Half-Monomer" Concept for Sequence Analysis of Condensation Copolymers by NMR

Pages 228-229 | Published online: 03 Jun 2010
 

Abstract

The "half-monomer" concept was introduced in 1982 by Devaux et al. [1]. The authors used Nuclear Magnetic Resonance (NMR) to characterize the copolymer obtained when mixing and heating at 290¼C poly(butylene terephthalate) (PBT for brief) together with poly(bisphenol A carbonate) (PC for brief). They noted that the repeat unit of PBT and of PC can be ideally split in two parts and thus they introduced four half-monomers A, B, C, D namely

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