Correlation between the nanomechanical characteristic and the phase transformation of BCC-based high entropy alloys produced via powder metallurgy

ABSTRACT

In this study, the effects of Cu addition on AlFeMnTiSi_0.75Cu_x (x = 0, 0.25, 0.5, 0.75, 1.00; in molar ratios) high entropy alloys (HEAs) prepared via mechanical alloying and spark plasma sintering were investigated. The structure, phase, morphology and composition of HEA powders were analysed and the results revealed that the AlFeMnTiSi_0.75Cu_x HEAs exhibited a multiphase structure. Additionally, after sintering at 900 °C, the formation of BCC, µ and L2₁ phases in the densified HEAs was enhanced. The investigation of the hardness, nanoindentation and compressive properties revealed that the microstructural and mechanical properties of AlFeMnTiSi_0.75Cu_x HEAs were improved at the optimal Cu fraction (0.25 molar ratio). The nanoindentation results revealed that the AlFeMnTiSi_0.75Cu_x HEAs exhibited the highest hardness and elastic modulus (H_IT = 19.2 GPa, E_IT = 336 GPa). These results improve the current understanding of multiphase HEAs and may pave way for the development of advanced HEAs with superior mechanical properties.

KEYWORDS:

• High entropy alloy
• multiphase
• compression
• nanoindentation
• mechanical alloying
• thermodynamic parameter

Acknowledgements

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (No. 2021R1A2C1005478).

Authors contribution

Hansung Lee: Conceptualisation, Methodology, Validation, Investigation, Visualisation, Writing – Original Draft, Writing – Review & Editing. Ashutosh Sharma: Resources, Writing – Original Draft, Writing – Review & Editing, Visualisation, Supervision. Minsu Kim: Experiment, Investigation. Byungmin Ahn: Conceptualisation, Writing – Review & Editing, Supervision, Project administration, Funding acquisition.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Data availability statement

The data required to reproduce these findings cannot be shared at this time, as the research data are confidential.