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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 14, 1981 - Issue 7
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Original Articles

Far-Infrared and Raman Spectra of Crystalline Tetrapropylammonium Trichloromercurate(II)

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Pages 553-562 | Received 01 May 1981, Accepted 25 Jun 1981, Published online: 06 Dec 2006
 

Abstract

The far-ir and Raman spectra of the tittle compound have been obtained at room and liquid nitrogen temperature. The spectra are consistent with a halogen bridged species and the vibrational modes are assigned in relation to the structure of the dimeric anionic complex. A symmetry lower than D2h is proposed in agreement with preliminary X-ray diffraction results.

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