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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 18, 1985 - Issue 6
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Original Articles

Theory of Overtone Vibrational Transitions with Application to the HF, DF and OH Emission Spectra

E. S. Medvedev Institute of Chemical Physics, Academy of Sciences of the USSR, 142432, Moscow Region, Chernogolovka, USSR
Pages 447-461 | Received 21 Feb 1985, Accepted 25 Mar 1985, Published online: 06 Dec 2006
 
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Abstract

The higher overtone band intensities are expressed in terms of the repulsive branch of the molecular potential, which can be characterized by a new molecular spectroscopic constant β. The β values are calculated from experimental band intensities.

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