On the Nature of the Imidazol-Link between Activated Carbon and Polymeric Iron Phthalocyanine Studied by Mössabauer Spectroscopy

J. Blomquist Institute of Physics, University of Stockholm Vanadisvagen 9, S-113 46, Stockholm, Sweden

U. Helgeson Institute of Physics, University of Stockholm Vanadisvagen 9, S-113 46, Stockholm, Sweden

L. C. Moberg Institute of Physics, University of Stockholm Vanadisvagen 9, S-113 46, Stockholm, Sweden

L. Y. Johansson Inorganic Chemistry 1, Chemical Center University of Lund, P.O. Box 124, 22100, Lund, Sweden

R. Larsson Inorganic Chemistry 1, Chemical Center University of Lund, P.O. Box 124, 22100, Lund, Sweden

B. Yom Tov Inorganic Chemistry 1, Chemical Center University of Lund, P.O. Box 124, 22100, Lund, Sweden

L. Jönsson Organic Chemistry 3, Chemical Center University of Lund, P.O. Box 124, 221 00, Lund, Sweden

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Abstract

Mössbauer spectroscopy is applied to a system of a polymeric iron phthalocyanine complex bonded to activated carbon via an imidazol molecule. This is covalently bonded to the carbon. It is concluded that the imidazol nitrogen coordinates1 primairly to iron in a central position of the condensed poly-ring system.

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On the Nature of the Imidazol-Link between Activated Carbon and Polymeric Iron Phthalocyanine Studied by Mössabauer Spectroscopy

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On the Nature of the Imidazol-Link between Activated Carbon and Polymeric Iron Phthalocyanine Studied by Mössabauer Spectroscopy

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