Abstract
Argon and mixtures of argon with CH4, C2H2 and N2 have been excited in a 27.2 MHz radio frequency discharge at pressures of 10 and 5 Torr. Plasma spectra have been recorded and analyzed. The excitation temperatures of Ar I and H, the C2 and CN vibrational temperatures and the N2 and CN rotational temperatures have been determined and discussed.